An ex-ambassador is not ambassador anybody. However, these days, no one pays attention to such niceties, which means that everybody pretty much gets called whatever. Just ask them.

Conversationally, i agree that ex-wife seems much more common that former wife. In writing, though, the use of former doesn't seem so rare. Here's an interesting ngram.

Los Angeles Rams CB Troy Hill Arrested On Suspicion of DUI - Turf Show

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